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Polymer nanocomposite : ウィキペディア英語版
Polymer nanocomposite

Polymer nanocomposites (PNC) consist of a polymer or copolymer having nanoparticles or nanofillers dispersed in the polymer matrix. These may be of different shape (e.g., platelets, fibers, spheroids), but at least one dimension must be in the range of 1–50 nm. These PNC's belong to the category of multi-phase systems (MPS, viz. blends, composites, and foams) that consume nearly 95% of plastics production. These systems require controlled mixing/compounding, stabilization of the achieved dispersion, orientation of the dispersed phase, and the compounding strategies for all MPS, including PNC, are similar.
Polymer nanoscience is the study and application of nanoscience to polymer-nanoparticle matrices, where nanoparticles are those with at least one dimension of less than 100 nm.
The transition from micro- to nano-particles lead to change in its physical as well as chemical properties. Two of the major factors in this are the increase in the ratio of the surface area to volume, and the size of the particle. The increase in surface area-to-volume ratio, which increases as the particles get smaller, leads to an increasing dominance of the behavior of atoms on the surface area of particle over that of those interior of the particle. This affects the properties of the particles when they are reacting with other particles. Because of the higher surface area of the nano-particles, the interaction with the other particles within the mixture is more and this increases the strength, heat resistance, etc. and many factors do change for the mixture.
An example of a nanopolymer is silicon nanospheres which show quite different characteristics; their size is 40–100 nm and they are much harder than silicon, their hardness being between that of sapphire and diamond.
==Bio-hybrid polymer nanofibers==
Many technical applications of biological objects like proteins, viruses or bacteria such as chromatography, optical information technology, sensorics, catalysis and drug delivery require their immobilization. Carbon nanotubes, gold particles and synthetic polymers are used for this purpose. This immobilization has been achieved predominantly by adsorption or by chemical binding and to a lesser extent by incorporating these objects as guests in host matrices.
In the guest host systems, an ideal method for the immobilization of biological objects and their integration into hierarchical architectures should be structured on a nanoscale to facilitate the interactions of biological nano-objects with their environment.
Due to the large number of natural or synthetic polymers available and the advanced techniques developed to process such systems to nanofibres, rods, tubes etc. make polymers a good platform for the immobilization of biological objects.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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